ZrO2含量对Bi2O3—B2O3—SiO2系封接玻璃结构性能的影响
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摘 要：采用熔融法制备了Bi2O3B2O3SiO2系封接玻璃.采用红外光谱、X射线衍射、综合热分析、电子扫描电镜、抗弯强度测试等表征方法研究了ZrO2含量对玻璃试样的结构、物相组成、软化温度、热膨胀系数、耐酸性和力学性能的影响.结果表明：当ZrO2质量分数低于4%时，玻璃试样中没有晶体析出；当ZrO2质量分数大于等于4%时，试样中有ZrO2和αBi2O3晶体析出.玻璃结构中主要存在[BO3]， [BO4]， [BiO3]， [SiO4]和[ZrO4]基团.当ZrO2质量分数小于3%时，随着ZrO2质量分数的增加，玻璃试样的转变温度Tg和软化温度Tf升高，膨胀系数降低，耐酸性增强，抗弯强度增加；当ZrO2质量分数为3%时，试样的Tg和Tf达到最大值为510 ℃和562 ℃，膨胀系数达到最小值6.92×10-6 K-1，抗弯强度达到最大值49 MPa；继续增加ZrO2的含量，玻璃试样的转变温度Tg和软化温度Tf降低，膨胀系数增大，耐酸性变差，抗弯强度降低.
关键词：ZrO2；Bi2O3；封接玻璃；耐酸性；膨胀系数
中图分类号：TG171 文献标识码：A
Abstract：Bi2O3B2O3SiO2 sealing glass was firstly prepared by melting method. The effect of ZrO2 content on the phase composition， softening temperature， thermal analysis， acid resistance， microstructure and mechanical properties of sealing glass was studied by infrared spectra， Xray diffraction analysis， thermal expansion coefficient testing， scanning electron microscopy and threepoint bending testing. The results showed that when the ZrO2 content was less than 4%， crystal did not occurred in the glass sample， as it is known that when the ZrO2 content was equal to or more than 4%， ZrO2 crystal and αBi2O3 was found in the glass sample. [BO3]， [BO4]， [BiO3]， [SiO4] and [ZrO4] groups are the main components of the sealing glass. When the ZrO2 content was less than 3% and with the increased amount of ZrO2， the softening...
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